Difference between revisions of "Ethylene"

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==Preparation==
 
==Preparation==
Ethylene can be prepared by dehydrating [[ethanol]] in gas phase using [[aluminium oxide]] as catalyst.
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Ethylene can be prepared by dehydrating [[ethanol]] in the gas phase using [[aluminium oxide]] as the catalyst.<ref>Hyperspace Pirate, ''Making Ethylene (Refrigerant R1150)'', [https://www.youtube.com/watch?v=UKFEbYdKdJg https://www.youtube.com/watch?v=UKFEbYdKdJg]</ref><ref>TheChemistryShack, ''How to Make Ethene (Ethylene) - Catalytic Dehydration of Ethanol'', [https://www.youtube.com/watch?v=I-10WJ_t4NQ https://www.youtube.com/watch?v=I-10WJ_t4NQ]</ref>
  
: CH<sub>3</sub>CH<sub>2</sub>OH → : C<sub>2</sub>H<sub>4</sub> + H<sub>2</sub>O
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: CH<sub>3</sub>CH<sub>2</sub>OH → C<sub>2</sub>H<sub>4</sub> + H<sub>2</sub>O
  
A more accessible way is to heat ethanol with concentrated [[sulfuric acid|sulfuric]] or [[phosphoric acid]] above 180 °C. [[Diethyl ether]] appears as side product if the temperature is too low.
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A more accessible way is to heat ethanol with concentrated [[sulfuric acid|sulfuric]] or [[phosphoric acid]] above 180 °C. [[Diethyl ether]] appears as a side product if the temperature is too low.
  
 
Destructive distillation of HDPE will produce lots of alkanes and alkenes, including ethylene.
 
Destructive distillation of HDPE will produce lots of alkanes and alkenes, including ethylene.
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===Storage===
 
===Storage===
Ethylene tanks must be kept in a cold place, away from light, heat and corrosive vapors.
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Ethylene tanks must be kept in a cold place, away from light, heat, and corrosive vapors.
  
 
===Disposal===
 
===Disposal===
Ethylene can be burned or released in air.
+
Ethylene can be burned or released in the air.
  
 
==References==
 
==References==

Latest revision as of 09:57, 30 July 2023

Ethylene
Ethene skeletal structure.png
Names
IUPAC name
Ethene
Systematic IUPAC name
Ethene
Identifiers
Jmol-3D images Image
Properties
C2H4
H2C=CH2
Molar mass 28.05 g/mol
Appearance Colorless gas
Odor Sweet
Density 1.178 kg/m3 (15 °C)
Melting point −169.2 °C (−272.6 °F; 104.0 K)
Boiling point −103.7 °C (−154.7 °F; 169.5 K)
2.9 mg/L
Solubility Soluble in acetone, benzene, diethyl ether
Solubility in ethanol 4.22 mg/L
Vapor pressure 5.21·104 mmHg (25 °C)
Acidity (pKa) 44
Thermochemistry
219.32 J·K−1·mol−1
52.47 kJ/mol
Hazards
Safety data sheet Praxair
Flash point −136 °C (−213 °F; 137 K)
Related compounds
Related compounds
Ethane
Acetylene
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Ethylene or ethene is a hydrocarbon which has the formula C2H4 or H2C=CH2. It is the simplest alkene.

Properties

Chemical

Ethylene is extremely flammable and will burn in an oxygen atmosphere.

C2H4 + 3 O2 → 2 CO2 + 2 H2O

Hydration of ethene yields ethanol.

Oxidation with peracids gives ethylene oxide.

Physical

Ethylene is a colorless gas at standard conditions, lighter than air, with a sweet odor and taste.

Availability

Ethylene is sold by gas companies in gas cylinders, as compressed gas.

Preparation

Ethylene can be prepared by dehydrating ethanol in the gas phase using aluminium oxide as the catalyst.[1][2]

CH3CH2OH → C2H4 + H2O

A more accessible way is to heat ethanol with concentrated sulfuric or phosphoric acid above 180 °C. Diethyl ether appears as a side product if the temperature is too low.

Destructive distillation of HDPE will produce lots of alkanes and alkenes, including ethylene.

Projects

  • Make ethylbenzene
  • Make ethylene oxide
  • Make polyethylene
  • Plant hormone for the ripening of fruits

Handling

Safety

Ethylene is very flammable and mixtures with air can be explosive. High concentrations in closed chambers pose an asphyxiating hazard, though being lighter than air, ethylene will not build-up in closed chambers easily.

Ethylene has anesthetic effects at high concentrations.

Storage

Ethylene tanks must be kept in a cold place, away from light, heat, and corrosive vapors.

Disposal

Ethylene can be burned or released in the air.

References

  1. Hyperspace Pirate, Making Ethylene (Refrigerant R1150), https://www.youtube.com/watch?v=UKFEbYdKdJg
  2. TheChemistryShack, How to Make Ethene (Ethylene) - Catalytic Dehydration of Ethanol, https://www.youtube.com/watch?v=I-10WJ_t4NQ

Relevant Sciencemadness threads