| IUPAC name
| Preferred IUPAC name
| Systematic IUPAC name
| Other names
Butter of antimony
|Molar mass||228.11 g/mol|
|Appearance||White deliquescent crystalline solid|
|Odor||Sharp, pungent (moist air)|
|Density|| 3.14 g/cm3 (25 °C)|
2.51 g/cm3 (150 °C)
|Melting point||73.4 °C (164.1 °F; 346.5 K)|
|Boiling point||223.5 °C (434.3 °F; 496.6 K)|
| 601.1 g/100 ml (0 °C)|
985.1 g/100 ml (25 °C)
1,357 g/100 ml (40 °C)
|Solubility|| Soluble in 1,4-dioxane, CS2, CCl4, chloroform, cyclohexane, CH2Cl2, diethyl ether, ethanol, selenium(IV) oxychloride, THF|
Insoluble in isopropylamine, pyridine, quinoline
|Solubility in acetic acid|| 143.9 g/100 g (0 °C)|
205.8 g/100 g (10 °C)
440.5 g/100 g (25 °C)
693.7 g/100 g (45 °C)
|Solubility in acetone||537.6 g/100 g (18 °C)|
|Solubility in benzoyl chloride|| 139.2 g/100 g (15 °C)|
169.5 g/100 g (25 °C)
2.76 kg/100 g (70 °C)
|Solubility in hydrochloric acid|| 20 °C|
8.954 g/ g (4.63% w/w)
8.576 g/ g (14.4% w/w)
7.898 g/ g (36.7% w/w)
|Solubility in p-Cymene|| 69.5 g/100 g (-3.5 °C)|
85.5 g/100 g (10 °C)
150 g/100 g (30 °C)
2.17 kg/100 g (70 °C)
|Vapor pressure|| 13.33 Pa (18.1 °C)|
0.15 kPa (50 °C)
2.6 kPa (100 °C)
Std enthalpy of
|Safety data sheet||Sigma-Aldrich|
|Lethal dose or concentration (LD, LC):|
LD50 (Median dose)
|525 mg/kg (oral, rat)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Antimony(III) chloride or antimony trichloride is a chemical compound with the formula SbCl3.
Antimony(III) chloride rapidly hydrolyzes in moist air to give antimony oxychloride.
- SbCl3 + H2O → SbOCl + 2 HCl
Visible hydrolysis is observed after 10 seconds of air exposure.
Antimony trichloride is a crystalline deliquescent solid, which readily hydrolyzes in moist air. It is soluble in ethers.
Antimony(III) chloride is sold by chemical suppliers, but it's difficult to get hold of due to its hazards.
Antimony trichloride is best purified from old or partially hydrolyzed reagent by subliming it under vacuum and condense it on a cold finger. The temperature at which vacuum sublimation begins is between 185-190 °C. Use a cold trap to prevent corrosive HCl and SbCl3 fumes from getting sucked up in the pump and destroying it.
- Carr-Price test (detection of vitamin A and related carotenoids)
- Make elemental antimony
- Make antimony organometallic compounds
Antimony trichloride readily hydrolyzes in the presence of moisture to release hydrochloric acid which is very corrosive. Contact with most protection gloves will cause them to darken.
Antimony compounds display moderate toxicity.
Antimony(III) chloride should be stored in dry air-tight containers, best in an inert atmosphere. Schlenk flasks are a common storage container. Ampouling is used for long term storage.
Antimony(III) chloride should be neutralized with a base then taken to a waste disposal center.
- Mabus - personal experience with the stuff; it's pretty nasty to work with and without a glovebox or Schlenk line it's almost impossible to do any kind of proper reactions.