Difference between revisions of "Hydrazine sulfate"

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| OtherNames = Hydrazine monosulfate
 
| OtherNames = Hydrazine monosulfate
 
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| ImageFile = Damp hydrazine sulfate by NileRed.png
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| ImageFile = Hydrazine_sulfate.jpg
| ImageSize = 280
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| ImageSize = 270
 
| ImageAlt =  
 
| ImageAlt =  
 
| ImageName =  
 
| ImageName =  
| ImageCaption = Hydrazine sulfate from urea and bleach
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| ImageCaption = Hydrazine sulfate via bleach/urea and methylethylketazine
 
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| LD50 = 601 mg/kg (rat, oral)
 
| LD50 = 601 mg/kg (rat, oral)
 
| LC50 =  
 
| LC50 =  
| MainHazards =  
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| MainHazards = Toxic
 
| NFPA-F =  
 
| NFPA-F =  
 
| NFPA-H =  
 
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| OtherFunction =  
 
| OtherFunction =  
 
| OtherFunction_label =  
 
| OtherFunction_label =  
| OtherCompounds = [[Hydrazine]]
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| OtherCompounds = [[Hydrazine hydrochloride]]<br>[[Hydrazine nitrate]]
 
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'''Hydrazine sulfate''' is a useful salt that finds its use as a non-volatile source of hydrazine.
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'''Hydrazine sulfate''' is a useful salt that finds its use as a non-volatile source of [[hydrazine]].
  
 
==Properties==
 
==Properties==
 
===Chemical===
 
===Chemical===
[[Hydrazine hydrate]] and [[hydrazine|anhydrous hydrazine]] are highly carcinogenic, toxic and air unstable compounds however as the sulfate salt, the hydrazine is much more stable and can be handled without much of the safety concerns as pure hydrazine. Hydrazine hydrate is produced when hydrazine sulfate is reacted with a strong base such as [[sodium hydroxide]].   
+
[[Hydrazine hydrate]] and anhydrous [[hydrazine]] are highly carcinogenic, toxic and air unstable compounds however as the sulfate salt, the hydrazine is much more stable and can be handled without much of the safety concerns as pure hydrazine. Hydrazine hydrate is produced when hydrazine sulfate is reacted with a strong base such as [[sodium hydroxide]].   
  
 
Hydrazine sulfate has the molecular formula N<sub>2</sub>H<sub>6</sub>SO<sub>4</sub>, however this is better represented as N<sub>2</sub>H<sub>5</sub>HSO<sub>4</sub>. It finds uses in organic chemistry, mainly by forming hydrazides.
 
Hydrazine sulfate has the molecular formula N<sub>2</sub>H<sub>6</sub>SO<sub>4</sub>, however this is better represented as N<sub>2</sub>H<sub>5</sub>HSO<sub>4</sub>. It finds uses in organic chemistry, mainly by forming hydrazides.
  
 
===Physical===
 
===Physical===
Hydrazine sulfate is a white crystalline solid melting at 254°C.
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Hydrazine sulfate is a white crystalline solid melting at 254 °C.
  
 
==Availability==
 
==Availability==
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===Disposal===
 
===Disposal===
Hydrazine sulfate can be neutralized with a diluted solution of calcium hypochlorite.
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Hydrazine sulfate can be neutralized with a diluted solution of [[calcium hypochlorite]].
 +
 
 +
==Gallery==
 +
<gallery widths="200" position="center" columns="4" orientation="none">
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Damp hydrazine sulfate by NileRed.png|Hydrazine sulfate from urea and bleach made by NileRed
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</gallery>
  
 
==References==
 
==References==
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[[Category:Inorganic compounds]]
 
[[Category:Inorganic compounds]]
 
[[Category:Nitrogen compounds]]
 
[[Category:Nitrogen compounds]]
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[[Category:Hydrazines]]
 
[[Category:Sulfates]]
 
[[Category:Sulfates]]
 
[[Category:Carcinogenic]]
 
[[Category:Carcinogenic]]

Latest revision as of 19:12, 2 May 2020

Hydrazine sulfate
Hydrazine sulfate.jpg
Hydrazine sulfate via bleach/urea and methylethylketazine
Names
IUPAC names
Hydrazinium hydrogen sulfate
Hydrazinium sulfate
Other names
Hydrazine monosulfate
Properties
N2H6SO4
N2H5HSO4
Molar mass 130.12 g/mol
Appearance White solid
Odor Odorless
Density 1.378 g/cm3
Melting point 254 °C (489 °F; 527 K) (decomposes)
Boiling point Decomposes
3 g/100 ml (20 °C)
14 g/100 ml (80 °C)
Solubility Insoluble in hydrocarbons
Solubility in ethanol 0.04 g/100 g (25 °C)
Vapor pressure ~0 mmHg
Hazards
Safety data sheet Sigma-Aldrich
Lethal dose or concentration (LD, LC):
601 mg/kg (rat, oral)
Related compounds
Related compounds
Hydrazine hydrochloride
Hydrazine nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Hydrazine sulfate is a useful salt that finds its use as a non-volatile source of hydrazine.

Properties

Chemical

Hydrazine hydrate and anhydrous hydrazine are highly carcinogenic, toxic and air unstable compounds however as the sulfate salt, the hydrazine is much more stable and can be handled without much of the safety concerns as pure hydrazine. Hydrazine hydrate is produced when hydrazine sulfate is reacted with a strong base such as sodium hydroxide.

Hydrazine sulfate has the molecular formula N2H6SO4, however this is better represented as N2H5HSO4. It finds uses in organic chemistry, mainly by forming hydrazides.

Physical

Hydrazine sulfate is a white crystalline solid melting at 254 °C.

Availability

Hydrazine sulfate is not very readily available for purchase to the amateur, but it is cheaply made at home.

Preparation

There are many ways in which an amateur can produce hydrazine sulfate. Two important ones which give decent, around 50%, yields are shown below.

Hypochlorite-Ketazine Process

Concentrated (20 - 30%) ammonia is mixed with methyl ethyl ketone and a few hundred mg of gelatin and cooled down to 0°C. Sodium hypochlorite is then added dropwise until the stoichiometric amount has been added. A hydrophobic azine (methyl ethyl ketazine) which is less dense than water, will then separate. This azine is then mixed with a stoichiometric amount of ~17% sulfuric acid, and heated to the boiling point of MEK to ensure full hydrolysis of the azine. Finally, the solution is chilled to 0°C to precipitate the hydrazine sulfate. The solution is then vacuum filtered.[1]

Hoffman Rearrangement of Urea

A solution of 10% sodium hypochlorite is added to solid sodium hydroxide and the mixture is kept cold during the addition.  Meanwhile, a solution of urea with a few hundred mg of gelatin is prepared. The two solutions are mixed and allowed to fully react, a voluminous foam will appear. After they have reacted, MEK is added to the solution and the azine is processed as previoulsy described.[2]

Projects

When mixed with a solution of silver nitrate, a silver mirror will be formed on the surface of the container. Hydrazine sulfate also finds a variety of uses in organic syntheses such as the preparation of 2,4 dinitrophenylhydrazine, and the preparation of luminol.

Free based hydrazine can be used in the production of sodium azide.

Handling

Safety

Hydrazine sulfate is much safer than its free base, hydrazine. However, it is still moderately toxic and a suspected carcinogen. It may ignite on contact with certain strong oxidizers.

Storage

Hydrazine sulfate can be safely stored in glass or plastic bottles, away from alkali.

Disposal

Hydrazine sulfate can be neutralized with a diluted solution of calcium hypochlorite.

Gallery

References

  1. https://www.youtube.com/watch?v=UB7vwIFCnR0
  2. https://www.youtube.com/watch?v=JCrDttuw5co

Relevant Sciencemadness threads