Anhydrous sodium carbonate
| IUPAC name
| Other names
|Molar mass|| 105.9888 g/mol (anhydrous)|
286.1416 g/mol (decahydrate)
|Density|| 2.54 g/cm3 (25 °C, anhydrous)|
1.92 g/cm3 (856 °C)
2.25 g/cm3 (monohydrate)
1.51 g/cm3 (heptahydrate)
1.46 g/cm3 (decahydrate)
|Melting point|| 851 °C (1,564 °F; 1,124 K) |
100 °C (212 °F; 373 K)
33.5 °C (92.3 °F; 306.6 K)
34 °C (93 °F; 307 K)
50.31 g/100 ml (29.9 °C)
48.1 g/100 ml (41.9 °C)
45.62 g/100 ml (60 °C)
43.6 g/100 ml (100 °C)
48.69 g/100 ml (34.8 °C)
7 g/100 ml (0 °C)
16.4 g/100 ml (15 °C)
34.07 g/100 ml (27.8 °C)
|Solubility|| Soluble in aq. alkalis, glycerol|
Slightly soluble in aq. alcohol, ethylene glycol
Insoluble in acetone, liq. ammonia, benzonitrile, CS2, ethanol, ethyl acetate
|Solubility in glycerol||98.3 g/100 g (15.5 °C)|
|Solubility in ethylene glycol||3.46 g/100 g (20 °C)|
|Solubility in dimethylformamide||0.05 g/100 g|
|Vapor pressure||~0 mmHg|
Std enthalpy of
|Safety data sheet|| Sigma-Aldrich (anhydrous)|
|Lethal dose or concentration (LD, LC):|
LD50 (Median dose)
|4,090 mg/kg (rat, oral)|
| Lithium carbonate|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Sodium carbonate, sometimes called washing soda or soda ash, is an inorganic weak base with chemical formula Na2CO3. One of few water-soluble carbonates, sodium carbonate finds abundant use as a cheap source of the carbonate ion, and also as a precursor to other sodium salts. Sodium carbonate occurs in nature as mineral Natrite.
Sodium carbonate will react with acids to form sodium salts and carbon dioxide.
- Na2CO3 + 2 HCl → 2 NaCl + H2O + CO2
- Na2CO3 + 2 HCOOH → 2 HCOONa + H2O + CO2
At very high temperatures, it decomposes to form sodium oxide and carbon dioxide.
- Na2CO3 → Na2O + CO2
However, unlike other carbonates, the decomposition of alkali carbonates is complicated.
Bubbling carbon dioxide in an aqueous solution of sodium carbonate will give sodium bicarbonate.
- Na2CO3 + H2O + CO2 → 2 NaHCO3
- Na2CO3 + H2O + SO2 → Na2SO3 + H2O + CO2
- Na2CO3 + H2O + 2 SO2 → 2 NaHSO3 + CO2
This route can be used to remove the sulfur dioxide produced from various reactions.
Sodium carbonate is often used in ore refining, in which it is fused with metal oxides at high temperatures to generate water-soluble compounds of the metal. An example of this is the roasting of chromium(III) oxide with sodium carbonate in the presence of oxygen to generate sodium dichromate.
- Na2CO3 + Cr2O3 + O2 → Na2Cr2O7 + CO2
Sodium carbonate is a white hydgoscopic compound, soluble in water but insoluble in organic solvents. It reacts with acids, sulfur and nitrogen oxides, as well as halogens, the reaction proceeding faster in the presence of water. Sodium carbonate crystallizes from water to form three different hydrates: monohydrate, heptahydrate and decahydrate.
Preparation and acquisition
Historically, sodium carbonate could be produced by leaching the ashes of burnt seaweed or glassworth, but this leads to an impure product. Today, sodium carbonate can be easily and cheaply prepared by the thermal decomposition of store-bought sodium bicarbonate (baking soda), which begins at 50 °C, but is more rapidly and completely accomplished at temperatures over 200 °C. Alternatively, it can be be purchased as washing soda or pH-increasing formulas in grocery or department stores, both of which are sometimes as cheap as $1/lb, or as soda ash, which is used as a mordant for textile dying.
Another convenient route is to add sodium hydroxide to ammonium carbonate or bicarbonate, then boil the solution until it dries completely. This produces sodium carbonate, while ammonia is produced as side-product. This route is attractive if you have old or contaminated sodium hydroxide, which you need to dispose of.
Lastly, leaving sodium hydroxide solution in open air will slowly form sodium carbonate. Make sure to do this in an area with clean air, as polluted air also contains sulfur and nitrogen oxides which will contaminate your sodium carbonate with sodium sulfate and sodium nitrate. Another problem, is that the resulting sodium carbonate will "grow" on the sides of your container and may even completely cover your container if you leave it long enough. Make sure to periodically check the evolution of the sodium carbonate.
As a basic sodium compound, the addition of most inorganic and some organic acids yields a sodium salt of that acid, and due to the almost universal solubility of sodium compounds, these salts can be used in preparing other metal salts of the same anion(for example, the preparation of the lesser-known copper aspirinate using sodium aspirinate and a soluble copper salt). Note that neutralizing a carbonate with an acid evolves large amounts of carbon dioxide and causes lots of bubbling. For this reason, Sodium hydroxide is most often used for titration.
Because many insoluble transition metal carbonates are used as precursors to salts of those metals, sodium carbonate is an invaluable reagent in forming a large number of compounds, first through precipitation of the insoluble carbonate in a double replacement reaction.
Sodium carbonate is non-toxic, though due to its desiccant properties it may irritate the skin.
Sodium carbonate should be stored in closed bottles, away from moisture and acidic vapors.
Sodium carbonate can be safely poured down the drain or dumped in trash. Avoid dumping it in the ground, as excess sodium is harmful to plants.
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